Nickel–cadmium battery

Type of rechargeable battery / From Wikipedia, the free encyclopedia

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The nickel–cadmium battery (Ni–Cd battery or NiCad battery) is a type of rechargeable battery using nickel oxide hydroxide and metallic cadmium as electrodes. The abbreviation Ni–Cd is derived from the chemical symbols of nickel (Ni) and cadmium (Cd): the abbreviation NiCad is a registered trademark of SAFT Corporation, although this brand name is commonly used to describe all Ni–Cd batteries.

Quick facts: Specific energy, Energy density, Specific pow...
Nickel–cadmium battery
From top to bottom: "Gumstick", AA, and AAA Ni–Cd batteries
Specific energy40–60 W·h/kg
Energy density50–150 W·h/L
Specific power150 W/kg
Charge/discharge efficiency70–90%[1]
Self-discharge rate10%/month
Cycle durability2,000 cycles
Nominal cell voltage1.2 V

Wet-cell nickel–cadmium batteries were invented in 1899. A Ni–Cd battery has a terminal voltage during discharge of around 1.2 volts which decreases little until nearly the end of discharge. The maximum electromotive force offered by a Ni–Cd cell is 1.3 V. Ni–Cd batteries are made in a wide range of sizes and capacities, from portable sealed types interchangeable with carbon-zinc dry cells, to large ventilated cells used for standby power and motive power. Compared with other types of rechargeable cells they offer good cycle life and performance at low temperatures with a fair capacity but their significant advantage is the ability to deliver practically their full rated capacity at high discharge rates (discharging in one hour or less). However, the materials are more costly than that of the lead–acid battery, and the cells have high self-discharge rates.

Sealed Ni–Cd cells were at one time widely used in portable power tools, photography equipment, flashlights, emergency lighting, hobby RC, and portable electronic devices. The superior capacity of nickel–metal hydride batteries, and recent lower cost, has largely supplanted Ni–Cd use. Further, the environmental impact of the disposal of the toxic metal cadmium has contributed considerably to the reduction in their use. Within the European Union, Ni–Cd batteries can now only be supplied for replacement purposes or for certain types of new equipment such as medical devices.[2]

Larger ventilated wet cell Ni–Cd batteries are used in emergency lighting, standby power, and uninterruptible power supplies and other applications.