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4-Hydroxybenzaldehyde
Chemical compound From Wikipedia, the free encyclopedia
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4‑Hydroxybenzaldehyde (para‑hydroxybenzaldehyde) is an organic compound with the formula C6H4OH(CHO).[4][5] Along with 2-hydroxybenzaldehyde and 3-hydroxybenzaldehyde, it is one of the three isomers of hydroxybenzaldehyde.
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Synthesis, reactions, uses
4-Hydroxybenzaldehyde is prepared by reaction of phenol with chloroform, which gives isomeric hydroxybenzal chlorides. Hydrolysis of the C-Cl bonds gives the aldehyde.[5]
4-Hydroxybenzaldehyde is a precursor to 4-hydroxyphenylglycine, a precursor to penicillins. In the Dakin oxidation, 4-hydroxybenzaldehyde reacts with hydrogen peroxide in base to form hydroquinone.
Metabolism and occurrence
p-Hydroxybenzaldehyde dehydrogenase is an enzyme found in carrots (Daucus carota).[6]
4-Hydroxybenzaldehyde is found in the orchids Gastrodia elata,[7] Galeola faberi,[8] and the Vanilla orchids.
See also
- Salicylaldehyde (2-hydroxybenzaldehyde)
References
Cited sources
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