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Gold(III) sulfide

Chemical compound From Wikipedia, the free encyclopedia

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Gold(III) sulfide or auric sulfide is an inorganic compound with the formula Au2S3. Auric sulfide has been described as a black and amorphous solid.[1] Only the amorphous phase has been produced, and the only evidence of existence is based on thermal analysis.

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Claims

Early investigations claimed to prepare auric sulfide by the reaction of lithium tetrachloroaurate with hydrogen sulfide:

2 Li[AuCl4] + 3 H2S → Au2S3 + 2 LiCl + 6 HCl

Similar preparations via chloroauric acid, auric chloride, or gold(III) sulfate a claimed proceed in anhydrous solvents, but water evinces a redox decomposition into metallic gold in sulfuric acid:[2][3][1]

8 Au3+ + 3 S2− + 12 H2O → 8 Au + 3 H2SO4 + 18 H+

Conversely, it is claimed that cyclo-octasulfur reduces gold(III) sulfate to a mixture of gold sulfides and sulfur oxides:[1]

Au2(SO4)3 + S8 → Au2S3 + Au2S + 4 SO3 + 6 SO2

Auric sulfide has also been claimed as the product when auric acetate is sonicated with cyclo-octasulfur in decalin.[3]

Auric sulfide is claimed to react with nitric acid as well sodium cyanide. It is claimed to dissolve in concentrated sodium sulfide solution.[1]

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See also

References

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