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Mercury(I) nitrate

Chemical compound From Wikipedia, the free encyclopedia

Mercury(I) nitrate
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Mercury(I) nitrate is an inorganic compound, a salt of mercury and nitric acid with the formula Hg2(NO3)2. A yellow solid, the compound is used as a precursor to other Hg22+ complexes. The structure of the hydrate has been determined by X-ray crystallography. It consists of a [H2O-Hg-Hg-OH2]2+ center, with a Hg-Hg distance of 254 pm.[3]

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It was first mentioned by Indian chemist Acharya Prafulla Chandra Ray in 1896.[4]

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Reactions

Mercury(I) nitrate is formed when elemental mercury is combined with dilute nitric acid (concentrated nitric acid will yield mercury(II) nitrate). Mercury(I) nitrate is a reducing agent which is oxidized upon contact with air.

Mercuric(II) nitrate reacts with elemental mercury(0) to form mercurous(I) nitrate (comproportionation reaction):[citation needed]

Hg(NO3)2 + Hg ⇌ Hg2(NO3)2

Solutions of mercury(I) nitrate are acidic due to slow reaction with water:

Hg2(NO3)2 + H2O ⇌ Hg2(NO3)(OH) + HNO3

Hg2(NO3)(OH) forms a yellow precipitate.

If the solution is boiled, or exposed to light, mercury(I) nitrate undergoes a disproportionation reaction yielding elemental mercury and mercury(II) nitrate:[5]

Hg2(NO3)2 ⇌ Hg + Hg(NO3)2

These reactions are reversible; the nitric acid formed can redissolve the basic salt.[citation needed]

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References

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