formula |
name |
other names |
structure |
Remarks |
references |
LiNiO2 |
lithium nickelate |
|
rhombohedral a = 2.88 Å, c = 14.2 Å, density = 4.78 / 4.81 |
|
[8] |
Li2NiO3 |
|
|
monoclinic C2/m a = 4.898 Å, b = 8.449 Å, c = 4.9692 Å, β = 109.02°, V = 194.60 Å3 |
Nickel in +4 state |
[1] |
NaNiO2 |
sodium nickelate |
|
monoclinic a = 5.33 Å, b = 2.86 Å, c = 5.59 Å, β = 110°30′, Z = 2, density = 4.74; over 220 °C: rhombohedral a = 2.96 Å, b = 15.77 Å |
Carbon dissolved in the molten salt can precipitate diamond. |
[8][9] |
KNiO2 |
potassium nickelate |
|
|
|
[8][10] |
SrTiNiO3[dubious – discuss] |
strontium titanate nickelate |
STN |
|
|
[11] |
YNiO3 |
yttrium nickelate |
|
monoclinic P21/n; orthorhombic a = 5.516 Å, b = 7.419 Å, c = 5.178 Å, V = 211.9 Å3, Z = 4, density = 6.13 |
insulator changes to metal under pressure |
[12][13] |
Y2BaNiO5 |
chain nickelate |
|
Orthorhombic Immm, a = 3.7589, b = 5.7604, c = 11.3311 |
|
[14][15] |
2H-AgNiO2 |
|
|
hexagonal P63/mmc, a = 2.93653 Å, b = 2.93653 Å, c = 12.2369 Å, V = 91.384 Å3, Z = 2, density = 7.216 g/cm3 |
Ni in +3 state |
[16] |
3R-AgNiO2 |
|
|
trigonal R32/m, a = 2.9390 Å, c = 18.3700 Å |
Ni in +3 state |
[16][17] |
Ag2NiO2 |
silveroxonickelate |
|
trigonal R32/m, a = 2.926 Å, c = 24.0888 Å |
lustrous black solid, stable in air; Ni3+ and subvalent Ag2+ |
[17] |
Ag3Ni2O4 |
|
|
hexagonal P63/mmc, a = 2.9331 Å, b = 2.9331 Å, c = 28.31 Å, V = 210.9 Å3, Z = 2, density = 7.951 g/cm3 |
electric conductor |
[18] |
BaNiO2 |
|
|
orthorhombic a = 5.73 Å, b = 9.2 Å, c = 4.73 Å, V = 249 Å3, Z = 4 |
black |
[19] |
BaNiO3 |
|
|
hexagonal a = 5.580 Å, c = 4.832 Å, V = 130.4 Å3, Z = 2 |
black powder dec 730 °C N-type semiconductor; decompose in acid |
[19][20] |
Ba2Ni2O5 |
|
|
hexagonal a = 5.72, c = 4.30, density = 6.4 |
black needles melt 1200 °C |
[19][20] |
LaNiO2 |
lanthanum nickelite |
|
a = 3.959, c = 3.375 |
Ni in +1 state |
[21] |
LaNiO3 |
lanthanum nickelate |
|
a = 5.4827 Å, b = 5.4827 Å, c = 3.2726 Å, γ = 120°, V = 345.5, Z = 6, density = 7.08 |
metallic, no insulating transition polar metal |
[22] |
La2NiO4 |
|
LN |
tetragonal a = 3.86 Å, b = 3.86 Å, c = 12.67 Å, V = 188.8 Å3, Z = 2, density = 7.05 |
|
[23][24] |
La3Ni2O6 |
|
|
tetragonal a = 3.968 Å, c = 19.32 Å |
|
[23] |
La3Ni2O7 |
|
|
a = 5.3961 Å, b = 5.4498 Å, c = 20.522 Å, V = 603.5, Z = 4, density = 7.1 |
superconductor under pressure Tc=80K |
[23][25][26] |
La4Ni3O8 |
|
|
|
antiferromagnetic below 105 K, mixed valence I and II |
[23][27] |
La4Ni3O10 |
|
|
|
|
[27] |
La2−xSrxNiO4 |
|
LSN |
a varies from 3.86 to 3.81 as x changes from 0 to 0.5, then ≈ 3.81; c ≈ 12.7 for x ≤ 0.8, the it falls to 12.4 at x = 1.2 |
polarization-specific metal |
[28] |
CeNiO3 |
cerium nickelate |
|
|
decomposes 1984 °C |
[29] |
PrNiO2 |
|
|
|
|
[23] |
PrNiO3 |
|
|
perovskite |
metallic insulator transition=130K |
[30] |
Pr4Ni3O8 |
|
|
|
|
[23] |
Pr2BaNiO5 |
chain nickelate |
|
Orthorhombic |
|
[14] |
La2PrNi2O7 |
|
|
orthorhombic |
|
[31] |
La2PrNi2O7 |
|
|
tetragonal |
Superconductor under pressure Tc = 82.5°C |
[31] |
NdNiO3 |
neodymium nickelate |
|
perovskite orthorhombic Pbnm, a = 5.38712 Å, b = 5.38267 Å, c = 7.60940 Å |
metallic insulator transition=200K |
[13][30] |
NdNiO2 |
|
|
orthorhombic a = 5.402 Å, b = 7.608 Å, c = 5.377 Å, V = 221.0 Å3, density = 7.54 |
|
[23][32][33] |
Nd4Ni3O8 |
|
|
orthorhombic a = 3.9171 Å, b = 3.9171 Å, c = 25.307 Å, V = 388.3 Å3, Z = 2, density = 7.54 |
|
[23][34] |
Nd2NiO4 |
|
|
Cmca a = 5.383 Å, b = 12.342 Å, c = 5.445 Å, V = 361.7 Å3, density = 7.55 |
|
[35] |
Nd2BaNiO5 |
chain nickelate |
|
Orthorhombic Immm, a = 2.8268 Å, b = 5.9272 Å, c = 11.651 Å |
|
[14][15] |
SmNiO3 |
samarium nickelate |
SNO |
perovskite Pnma, a = 5.431 Å, b = 7.568 Å, c = 5.336 Å, V = 219.3 Å, Z = 4, density = 7.79 |
metallic insulator transition=400K |
[30][36] |
Sm1.5Sr0.5NiO4 |
|
SSNO |
orthorhombic Bmab |
giant dielectric constant 100,000 |
[37] |
EuNiO3 |
europium nickelate |
|
perovskite orthorhombic a = 5.466 Å, b = 7.542 Å, c = 5.293 Å, V = 218.2 Å3, Z = 4, density = 7.87 |
metallic insulator transition=460K |
[30] |
GdNiO3 |
gadolinium nickelate |
|
perovskite orthorhombic a = 0.5492 Å, b = 0.7506 Å, c = 0.5258 Å, V = 216.8 Å3, Z = 4, density = 8.09 |
metallic insulator transition=510.9K |
[38] |
Gd2NiO4 |
digadolinium nickelate |
|
Orthorhombic a = 3.851 Å, b = 3.851 Å, c = 6.8817 Å, V = 187.5 Å3, Z = 2, density = 7.75 |
|
[39] |
BaGd2NiO5 |
barium digadolinium nickelate |
chain nickellate |
?orthorhombic |
low thermal conductance |
[40] |
Tb2BaNiO5 |
chain nickelate |
|
Orthorhombic |
|
[14] |
DyNiO3 |
dysprosium nickelate |
|
perovskite orthorhombic a = 0.55 Å, b = 0.7445 Å, c = 0.5212 Å V=213.4 Z=4 density=8.38 |
metallic insulator transition=564.1K |
[30][38][41] |
Dy2BaNiO5 |
chain nickelate |
|
Orthorhombic |
|
[14] |
HoNiO3 |
holmium nickelate |
|
perovskite orthorhombic a = 3.96 Å, b = 3.96 Å, c = 5.04 Å, V = 212 Å3 Z = 4, density=8.51 |
metallic insulator transition=560K |
[38] |
Ho2BaNiO5 |
chain nickelate |
|
Orthorhombic Immm, a = 3.764 Å, b = 5.761 Å, c=11.336 Å |
|
[14][42] |
ErNiO3 |
erbium nickelate |
|
perovskite orthorhombic a = 5.514 Å, b =7.381 Å, c = 5.16 V=201 Z=4 density=8.67 |
metallic insulator transition=580K |
[38][43] |
Er2BaNiO5 |
chain nickelate |
|
Orthorhombic Immm a = 3.7541 Å, b = 5.7442 Å c=11.3019 Å V=243.71 Å3 Z=2 |
|
[14][15][44] |
TmNiO3 |
thulium nickelate |
|
orthorhombic a = 5.495 Å, b = 7.375 Å, c = 5.149 Å V = 208.7 Z = 4 density = 8.77 |
|
[45] |
Tm2BaNiO5 |
thulium barium nickelate |
|
Orthorhombic low temperature Pnma a = 12.2003 Å b = 5.65845 Å c = 6.9745 Å Z = 4; high T: Immm a = 3.75128 b = 5.7214 c = 11.2456 |
Pnma form is brown Immm form is dark green |
[14][46] |
YbNiO3 |
ytterbium nickelate |
|
Orthorhombic a = 5.496 Å, b = 7.353 Å, c = 5.131 Å Z=4 V=207.4 Å3 density=8.96 |
|
[47] |
Yb2BaNiO5 |
ytterbium barium nickelate |
|
Orthorhombic Pnma a = 5.6423 Å, b = 6.9545 Å, c = 12.1583 Å V=477.1 Z=4 density=8.66 |
Pnma form is brown |
[46] |
LuNiO3 |
lutetium nickelate |
|
perovskite a = 5.499 Å, b = 7.356 Å, c = 5.117 Å, V = 207 Å3, Z = 4, density = 9.04 |
metallic insulator transition=600K |
[38][48] |
Lu2BaNiO5 |
|
|
Orthorhombic Pnma |
|
[15] |
TlNiO3 |
thallium nickelate(III) |
|
perovskite a = 5.2549 Å, b = 5.3677 Å, c = 7.5620 Å, V = 213.3 Å3 |
|
[49] |
PbNiO3 |
|
BiNiO3 |
bismuth nickelate(III) |
|
perovskite triclinic a = 5.3852, b = 5.6498, c = 7.7078 Å, α = 91.9529°, β = 89.8097°, γ = 91.5411, V = 234.29 Å3 |
Ni in +2 state, Bi in +3 and +5; stable 5–420K, antiferromagnetic |
[50][51] |