Relaxor ferroelectric

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Relaxor ferroelectrics are ferroelectric materials that exhibit high electrostriction. As of 2015, although they have been studied for over fifty years,[1] the mechanism for this effect is still not completely understood, and is the subject of continuing research.[2][3][4][5]

Examples of relaxor ferroelectrics include:

  • lead magnesium niobate (PMN) [6][7][8]
  • lead magnesium niobate-lead titanate (PMN-PT) [9]
  • lead lanthanum zirconate titanate (PLZT)[10]
  • lead scandium niobate (PSN) [11]
  • Barium Titanium-Bismuth Zinc Niobium Tantalum (BT-BZNT)[12]
  • Barium Titanium-Barium Strontium Titanium (BT-BST) [13]

Applications

Relaxor Ferroelectric materials find application in high efficiency energy storage and conversion as they have high dielectric constants, orders-of-magnitude higher than those of conventional ferroelectric materials. Like conventional ferroelectrics, Relaxor Ferroelectrics show permanent dipole moment in domains. However, these domains are on the nano-length scale, unlike conventional ferroelectrics domains that are generally on the micro-length scale, and take less energy to align. Consequently, Relaxor Ferroelectrics have very high specific capacitance and have thus generated interest in the fields of energy storage.[10] Furthermore, due to their slim hysteresis curve with high saturated polarization and low remnant polarization, Relaxor ferroelectrics have high discharge energy density and high discharge rates. BT-BZNT Multilayer Energy Storage Ceramic Capacitors (MLESCC) were experimentally determined to have very high efficiency(>80%) and stable thermal properties over a wide temperature range.[12]

References

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