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Isotopes of titanium
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Naturally occurring titanium (22Ti) is composed of five stable isotopes; 46Ti, 47Ti, 48Ti, 49Ti and 50Ti with 48Ti being the most abundant (73.8% natural abundance). Twenty-one radioisotopes have been characterized, with the most stable being 44Ti with a half-life of 60 years, 45Ti with a half-life of 184.8 minutes, 51Ti with a half-life of 5.76 minutes, and 52Ti with a half-life of 1.7 minutes. All of the remaining radioactive isotopes have half-lives that are less than 33 seconds, and the majority of these have half-lives that are less than half a second.[4]
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The isotopes of titanium range in atomic mass from 39.00 u (39Ti) to 64.00 u (64Ti). The primary decay mode for isotopes lighter than the stable isotopes (lighter than 46Ti) is β+ and the primary mode for the heavier ones (heavier than 50Ti) is β−; their respective decay products are scandium isotopes and the primary products after are vanadium isotopes.[4]
Two stable isotopes of titanium (47Ti and 49Ti) have non-zero nuclear spin of 5/2- and 7/2-, respectively, and thus are NMR-active.[5]
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List of isotopes
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- mTi – Excited nuclear isomer.
- ( ) – Uncertainty (1σ) is given in concise form in parentheses after the corresponding last digits.
- # – Atomic mass marked #: value and uncertainty derived not from purely experimental data, but at least partly from trends from the Mass Surface (TMS).
- # – Values marked # are not purely derived from experimental data, but at least partly from trends of neighboring nuclides (TNN).
- Modes of decay:
EC: Electron capture n: Neutron emission p: Proton emission - Bold symbol as daughter – Daughter product is stable.
- ( ) spin value – Indicates spin with weak assignment arguments.
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Titanium-44
Titanium-44 (44Ti) is a radioactive isotope of titanium that undergoes electron capture to an excited state of scandium-44 with a half-life of 60 years, before the ground state of 44Sc and ultimately 44Ca are populated.[7] Because titanium-44 can only decay through electron capture, its half-life increases with its ionization state and it becomes stable in its fully ionized state (that is, having a charge of +22).[8]
Titanium-44 is produced in relative abundance in the alpha process in stellar nucleosynthesis and the early stages of supernova explosions.[9] It is produced when calcium-40 fuses with an alpha particle (helium-4 nucleus) in a star's high-temperature environment; the resulting 44Ti nucleus can then fuse with another alpha particle to form chromium-48. The age of supernovae may be determined through measurements of gamma-ray emissions from titanium-44 and its abundance.[8] It was observed in the Cassiopeia A supernova remnant and SN 1987A at a relatively high concentration, a consequence of delayed decay resulting from ionizing conditions.[7][8]
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References
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