乙酸金(III)
維基百科，自由的百科全書
| 乙酸金(III) | |
|---|---|
| 英文名 | Gold(III) acetate |
| 別名 | 醋酸金 |
| 識別 | |
| CAS號 | 15804-32-7 |
| SMILES |
|
| InChI |
|
| InChIKey | OTCKNHQTLOBDDD-UHFFFAOYSA-K |
| 性質 | |
| 化學式 | Au(O2CCH3)3 |
| 摩爾質量 | 374.10 g·mol⁻¹ |
| 熔點 | 140 °C（分解） |
| 溶解性（水） | 低 |
| 若非註明，所有數據均出自一般條件（25 ℃，100 kPa）下。 | |
乙酸金(III)是一種化合物，化學式為Au(CH3COO)3，是棕色、對靜電敏感的固體。[1]它可由氫氧化金和乙酸反應製得。[2]它可用於製備金納米顆粒。[3]
化學性質
- Au(CH3COO)3 + C6H5N → (C6H5N)Au(CH3COO)3
它和2,2'-聯吡啶在類似的條件下反應，得到[Au(CH3COO)2(bipy)][Au(CH3COO)4]。[1]
參考文獻
- ^ 1.0 1.1 1.2 Langseth, Eirin. Synthesis and Reactivity of Gold(III) Complexes （頁面存檔備份，存於互聯網檔案館）（original link （頁面存檔備份，存於互聯網檔案館））. Retrieved Feb 14 2020.
- ^ Leslie F. Warren, Jr.Patricia H. Cunningham. Method of producing a gold film. US4933204A
- ^ Shariq, Mohammed; Majerič, Peter; Friedrich, Bernd; Budic, Bojan; Jenko, Darja; Dixit, Amit Rai; Rudolf, Rebeka. Application of Gold(III) Acetate as a New Precursor for the Synthesis of Gold Nanoparticles in PEG Through Ultrasonic Spray Pyrolysis. Journal of Cluster Science. 2017, 28 (3): 1647–1665. ISSN 1040-7278. doi:10.1007/s10876-017-1178-0.
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| 乙酸鹽及乙酸衍生物 | |||||||||||||||||||||||||||||||||||||||||||||||||
|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
| AcH AcOH |
He | ||||||||||||||||||||||||||||||||||||||||||||||||
| LiOAc | Be(OAc)2 Be4O(OAc)6 |
B(OAc)3 | ROAc | NH4AcO | AcOAc | FAc | Ne | ||||||||||||||||||||||||||||||||||||||||||
| NaOAc NaH(OAc)2 |
Mg(OAc)2 | Al(OH)2(OAc) Al(OH)(OAc)2 Al(OAc)3 Al(OAc)x |
Si | P | S | ClAc ClOAc |
Ar | ||||||||||||||||||||||||||||||||||||||||||
| KOAc | Ca(OAc)2 | Sc(OAc)3 | Ti(OAc)4 | VO2(OAc)2 | Cr2(OAc)4 Cr(OAc)3 |
Mn(OAc)2 Mn(OAc)3 |
Fe(OAc)2 Fe(OAc)3 |
Co(OAc)2 Co(OAc)3 |
Ni(OAc)2 | Cu2(OAc)2 Cu2(OAc)4 |
Zn(OAc)2 | Ga(OAc)3 | Ge | As | Se | BrAc BrOAc |
Kr | ||||||||||||||||||||||||||||||||
| RbOAc | Sr(OAc)2 | Y(OAc)3 | Zr(OAc)4 | Nb | Mo(OAc)2 | Tc | Ru(OAc)3 | Rh2(OAc)4 | Pd(OAc)2 | AgOAc | Cd(OAc)2 | In(OAc)3 | Sn(OAc)2 Sn(OAc)4 |
Sb(OAc)3 | Te | IAc IOAc I(OAc)3 |
Xe | ||||||||||||||||||||||||||||||||
| CsOAc | Ba(OAc)2 | Hf | Ta | W | Re | Os | Ir | Pt | Au(OAc)3 | Hg2(OAc)2, Hg(OAc)2 |
TlOAc Tl(OAc)3 |
Pb(OAc)2 Pb(OAc)4 |
Bi(OAc)3 | Po | At | Rn | |||||||||||||||||||||||||||||||||
| Fr | Ra | Rf | Db | Sg | Bh | Hs | Mt | Ds | Rg | Cn | Nh | Fl | Mc | Lv | Ts | Og | |||||||||||||||||||||||||||||||||
| ↓ | |||||||||||||||||||||||||||||||||||||||||||||||||
| La(OAc)3 | Ce(OAc)3 Ce(OAc)4 |
Pr(OAc)3 | Nd(OAc)3 | PmAc3 | Sm(OAc)3 | Eu(OAc)3 | Gd(OAc)3 | Tb(OAc)3 | Dy(OAc)3 | Ho(OAc)3 | Er(OAc)3 | Tm(OAc)3 | Yb(OAc)3 | Lu(OAc)3 | |||||||||||||||||||||||||||||||||||
| Ac(OAc)3 | Th(OAc)4 | Pa | U(OAc)4 UO2(OAc)2 |
Np | PuO2Ac2 | Am | Cm | Bk | Cf | Es | Fm | Md | No | Lr | |||||||||||||||||||||||||||||||||||
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