氰化鋁

氰化鋁是一種無機化合物，化學式為Al(CN)₃。它可由氰化氫和氫化鋁反應製得。^[1]四氯合鋁酸鋰和三甲基氰矽烷在乙醚中反應，也能得到氰化鋁。^[2]金屬鋁和氰化汞在液氨中反應，可以得到氰化鋁的氨合物。^[3]它在水中水解，生成氫氧化鋁和氰化氫；^[1]它難溶於吡啶。^[4]

AlH₃+3 HCN → Al(CN)₃+3 H₂

Al(CN)₃+3 H₂O → Al(OH)₃+3 HCN

氰化鋁
IUPAC名 Aluminium tricyanide
識別
CAS號	87993-97-3  Y
PubChem	21122287
ChemSpider	19984794
SMILES	[C-]#N.[C-]#N.[C-]#N.[Al+3]
性質
化學式	C3AlN3
摩爾質量	105.03 g·mol−1
若非註明，所有數據均出自標準狀態（25 ℃，100 kPa）下。

參考文獻

1. Wittig, Georg; Bille, Heinz. Aluminum tricyanide and lithium aluminum tetracyanide. Zeitschrift fuer Naturforschung, 1951. 6B. 226. ISSN: 0372-9516.
2. Darrick Williams, Brett Pleune, Kurt Leinenweber, J. Kouvetakis. Synthesis and Structural Properties of the Binary Framework C–N Compounds of Be, Mg, Al, and Tl. Journal of Solid State Chemistry. 2001-06, 159 (1): 244–250 [2020-06-26]. doi:10.1006/jssc.2001.9192. （原始內容存檔於2018-06-04） （英語）.
3. Bergstrom, F. W. The Reaction Between Mercuric Cyanide and Certain Metals in Liquid Ammonia. Journal of the American Chemical Society. July 1924, 46 (7): 1559–1568. doi:10.1021/ja01672a002.
4. A. V. G. Chizmeshya, C. J. Ritter, T. L. Groy, J. B. Tice, J. Kouvetakis. Synthesis of Molecular Adducts of Beryllium, Boron, and Gallium Cyanides: Theoretical and Experimental Correlations between Solid-State and Molecular Analogues. Chemistry of Materials. 2007-11, 19 (24): 5890–5901 [2020-06-26]. ISSN 0897-4756. doi:10.1021/cm071275h （英語）.