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砷化鉍

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砷化鉍
英文名 bismuth arsenide
識別
CAS號 12322-23-5  ✓
性質
化學式 BiAs
摩爾質量 283.9 g·mol⁻¹
外觀 固體
若非註明,所有數據均出自一般條件(25 ℃,100 kPa)下。

砷化鉍是一種無機化合物,化學式為BiAs。它的α型[1]和β型[2]結構均有理論計算的報道。

製備

砷化鉍可由三氯化鉍甲苯溶液和三(三甲基矽基)砷在室溫反應得到:[3]

BiCl3 + As[Si(CH3)3]3 → BiAs + 3(CH3)3SiCl

參考文獻

  1. ^ Wen-Zhi Xiao, Gang Xiao, Qing-Yan Rong, Ling-Ling Wang. New two-dimensional V-V binary compounds with a honeycomb-like structure: a first-principles study. Materials Research Express. 2018-03-07, 5 (3): 035903 [2020-04-25]. ISSN 2053-1591. doi:10.1088/2053-1591/aab06c. 
  2. ^ C. Y. Wu, L. Sun, J. C. Han, H. R. Gong. Band structure, phonon spectrum, and thermoelectric properties of β-BiAs and β-BiSb monolayers. Journal of Materials Chemistry C. 2020, 8 (2): 581–590 [2020-04-25]. ISSN 2050-7526. doi:10.1039/C9TC04842A (英語). 
  3. ^ Geoff C. Allen, Claire J. Carmalt, Alan H. Cowley, Andrew L. Hector, Smuruthi Kamepalli, Yvonne G. Lawson, Nicholas C. Norman, Ivan P. Parkin, Laura K. Pickard. Preparation and Characterization of a Material of Composition BiP (Bismuth Phosphide) and Other Intergroup 15 Element Phases. Chemistry of Materials. 1997-06, 9 (6): 1385–1392 [2020-04-25]. ISSN 0897-4756. doi:10.1021/cm960606f (英語). 
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砷化鉍
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