Elbs過硫酸鹽氧化反應
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Elbs過硫酸鹽氧化反應(Elbs persulfate oxidation)
反應機理
酚鹽負離子在酚羥基對位對過二硫酸根離子中的過氧原子進行親核進攻,硫酸根離子離去,產生對二酚的硫酸酯,經水解得二酚。[5]
參見
參考資料
- ^ Elbs, K. J. Prakt. Chem. 1893, 48, 179.
- ^ S. M. Sethna. The Elbs Persulfate Oxidation. Chem. Rev. 1951, 49 (1): 91–101. doi:10.1021/cr60152a002.
- ^ Lee, J. B.; Uff, B. C. Quart. Rev. 1967, 21, 453. (綜述)
- ^ Behrman, E. J. Org. React. 1988, 35, 421-511. (綜述)
- ^ E. J. Behrman. The Elbs and Boyland-Sims peroxydisulfate oxidations. Beilstein Journal of Organic Chemistry. 2006, 2 (1): 22. doi:10.1186/1860-5397-2-22.
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