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十甲基二茂钌

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十甲基二茂钌
英文名 Decamethylruthenocene
别名 双(五甲基环戊二烯)钌(II)
识别
CAS号 84821-53-4  ✓
SMILES
性质
化学式 C20H30Ru
摩尔质量 371.52 g·mol−1
若非注明,所有数据均出自一般条件(25 ℃,100 kPa)下。

十甲基二茂钌是一种有机钌化合物,化学式为C20H30Ru,可简写为Cp*2Ru。它可由三氯化钌五甲基环戊二烯反应得到,[1]反应产生的另一产物是五甲基环戊二烯基二氯化钌二聚体英语Pentamethylcyclopentadienyl ruthenium dichloride dimer[2]它和三甲基膦反应,得到Cp*Ru(PMe3)2Cl。[1]它可以被[3][4]氧化。

参考文献

  1. ^ 1.0 1.1 T. Don Tilley, Robert H. Grubbs, John E. Bercaw. Halide, hydride, and alkyl derivatives of (pentamethylcyclopentadienyl)bis(trimethylphosphine)ruthenium. Organometallics. 1984-02, 3 (2): 274–278 [2020-08-01]. ISSN 0276-7333. doi:10.1021/om00080a019. (原始内容存档于2019-09-22) (英语). 
  2. ^ U. Koelle, J. Kossakowski, D. Grumbine, T. Don Tilley. Di-μ-Chloro-Bis[(η 5 -Pentamethylcyclopentadienyl) Chlororuthenium(III)], [Cp * RuCl 2 ] 2 and Di-μ-methoxo-Bis(η 5 -Pentamethylcyclopentadienyl)diruthenium(II), [Cp * RuOMe] 2. John Wiley & Sons, Inc. 2007-01-05: 225–228 [2020-08-01]. ISBN 9780470132609. doi:10.1002/9780470132609.ch52. 
  3. ^ A. A. Kamyshova, A. Z. Kreindlin, P. V. Petrovskii, A. S. Peregudov, Yu. A. Borisov, A. A. Koridze. Functionalization of one or two methyl groups in the [Cp*2RuBr]+Br− complex in the reaction with bromine. Russian Chemical Bulletin. 2005-12, 54 (12): 2805–2812 [2020-08-01]. ISSN 1066-5285. doi:10.1007/s11172-006-0194-2 (英语). 
  4. ^ Michel O. Albers, David C. Liles, David J. Robinson, Alan. Shaver, Eric. Singleton, Manfred B. Wiege, Jan C. A. Boeyens, Demetrius C. Levendis. Chemistry of cyclopentadienylruthenium and -osmium complexes. 3. New high-yield syntheses of ruthenocenes and osmocenes. The crystal and molecular structures of decamethylruthenocene and decamethylosmocene. Organometallics. 1986-11, 5 (11): 2321–2327 [2020-08-01]. ISSN 0276-7333. doi:10.1021/om00142a025 (英语). 
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十甲基二茂钌
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