四氯化五甲基环戊二烯基钽 - Wikiwand
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四氯化五甲基环戊二烯基钽

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四氯化五甲基环戊二烯基钽
识别
CAS号 71414-47-6  ✓
性质
化学式 C10H15Cl4Ta
摩尔质量 457.99 g·mol−1
外观 橙黄色粉末[1]
黄色晶体[2]
若非注明,所有数据均出自一般条件(25 ℃,100 kPa)下。

四氯化五甲基环戊二烯基钽是一种金属有机化合物,化学式为C10H15TaCl4。它可由五氯化钽和三丁基(五甲基环戊二烯基)锡(或(5-三甲基硅基)五甲基环戊二烯[1])在甲苯中反应得到。[3]它在反应中氯可以被其它配体取代。[4][5]

参考文献

  1. ^ 1.0 1.1 Zachary J. Tonzetich, Richard Eisenberg. Luminescent η5-pentamethylcyclopentadienyl tantalum(V) complexes: synthesis, characterization, and emission spectroscopy. Inorganica Chimica Acta. 2003-03, 345: 340–344 [2020-12-09]. doi:10.1016/S0020-1693(02)01276-8. (原始内容存档于2018-06-22) (英语). 
  2. ^ Robert D. Sanner, Steven T. Carter, William J. Bruton. The preparation of mono(η5-pentamethylcyclopentadienyl) compounds of tantalum(V). Journal of Organometallic Chemistry. 1982-12, 240 (2): 157–162 [2020-12-09]. doi:10.1016/S0022-328X(00)82510-3. (原始内容存档于2018-06-14) (英语). 
  3. ^ Endy Y.-J. Min, John E. Bercaw, Shujian Chen, Zi-Ling Xue. Gregory S. Girolami, Alfred P. Sattelberger , 编. Bis(η 5 -Pentamethylcyclopentadienyl) Complexes of Niobium and Tantalum. Hoboken, NJ, USA: John Wiley & Sons, Inc. 2014-04-11: 52–57 [2020-12-09]. ISBN 9781118744994. doi:10.1002/9781118744994.ch11. 
  4. ^ Koushik Saha, Sagar Ghorai, Sourav Kar, Suvam Saha, Rajarshi Halder, Beesam Raghavendra, Eluvathingal D. Jemmis, Sundargopal Ghosh. Stabilization of Classical [B 2 H 5 ] − : Structure and Bonding of [(Cp*Ta) 2 (B 2 H 5 )(μ‐H)L 2 ] (Cp*=η 5 ‐C 5 Me 5 ; L=SCH 2 S). Angewandte Chemie International Edition. 2019-12-02, 58 (49): 17684–17689 [2020-12-09]. ISSN 1433-7851. doi:10.1002/anie.201911480 (英语). 
  5. ^ Koushik Saha, Urminder Kaur, Beesam Raghavendra, Sundargopal Ghosh. Role of Metals and Thiolate Ligands in the Structures and Electronic Properties of Group 5 Bimetallic–Thiolate Complexes. Inorganic Chemistry. 2020-09-08, 59 (17): 12494–12503 [2020-12-09]. ISSN 0020-1669. doi:10.1021/acs.inorgchem.0c01588. (原始内容存档于2020-11-13) (英语). 
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四氯化五甲基环戊二烯基钽
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