氟三碘甲烷

氟三碘甲烷
	IUPAC名; Fluoro(triiodo)methane
别名	Fluorotriiodomethane
识别
CAS号	1495-49-4
PubChem	23510639
ChemSpider	11570071
SMILES	C(F)(I)(I)I;
InChI	InChI=1S/CFI3/c2-1(3,4)5;
InChIKey	GXKSSISYTXERRQ-UHFFFAOYSA-N
性质
化学式	CFI3
摩尔质量	411.72 g·mol−1
密度	3.847±0.06 g·cm−3
沸点	204.5±8.0 °C
溶解性（水）	0.04 g/100 mL
	若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。

氟三碘甲烷是一种甲烷衍生化合物，化学式C F I₃。^[2]^[3]^[4]它可以在三氟碘甲烷的辐解中产生，产生机理源自于反应中生成的:CFI和I₂或CF₃I的反应。^[5]^[6]它的生成热−ΔH_f^θ为−2 kcal·mol⁻¹，而CI₃X的氯代或溴代物的值要更负。^[7]

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参考文献

[1]
Calculated using Advanced Chemistry Development (ACD/Labs) Software V11.02 (© 1994-2019 ACD/Labs). Retrieved from SciFinder. [2019-3-23]
[2]
fluorotriiodomethane. NIST. wtt-pro.nist.gov. [7 June 2017]. （原始内容存档于2020-12-12）.
[3]
fluorotriiodomethane. webbook.nist.gov. [7 June 2017]. （原始内容存档于2019-11-16）.
[4]
Gurvich, L. V.; Veyts, I. Thermodynamic Properties of Individual Substances: Elements and Compounds. CRC Press. September 1, 1990: 185 [2019-03-23]. ISBN 9780891165330. （原始内容存档于2019-09-02）.
[5]
Nozomi Nakayama, Elizabeth E. Ferrenz, Denise R. Ostling, Andrea S. Nichols, Janelle F. Faulk, Christopher R. Arumainayagam. Surface Chemistry and Radiation Chemistry of Trifluoroiodomethane (CF 3 I) on Mo(110). The Journal of Physical Chemistry B. 2004-4, 108 (13): 4080–4085 [2019-03-23]. ISSN 1520-6106. doi:10.1021/jp0310192. （原始内容存档于2021-02-19）（英语）. 请检查|date=中的日期值 (帮助)
[6]
Mahesh Rajappan, Lin L Zhu, Jizhou Wang, Graeme Gardner, Kevin Bu, Huiliang Mai, Madeleine Laupheimer, Yomay Shyur, Nuriesya S Abu Bakar, Samantha K Skinner-Hall, Christina Kim, Jaclyn M Haskins, Christopher R Arumainayagam. The role of low-energy electrons in the high-energy radiolysis of condensed CF 3 I. Journal of Physics: Condensed Matter. 2010-03-03, 22 (8): 084006 [2019-03-23]. ISSN 0953-8984. doi:10.1088/0953-8984/22/8/084006.
[7]
Maslov, P. G.; Maslov, Yu. P. Heats of formation of halogen derivatives of methane and ethylene. Khimiya i Tekhnologiya Topliv i Masel, 1958. 3 (10): 50-55, ISSN 0023-1169.

拓展阅读

Sladkov, I. B.; Bogacheva, A. V. Critical parameters of mixed halides of carbon. Zhurnal Prikladnoi Khimii (Sankt-Peterburg, Russian Federation), 1991. 64 (11): 2435-2437. ISSN: 0044-4618.

[ACD-1] [1]
Calculated using Advanced Chemistry Development (ACD/Labs) Software V11.02 (© 1994-2019 ACD/Labs). Retrieved from SciFinder. [2019-3-23]

[2] [2]
fluorotriiodomethane. NIST. wtt-pro.nist.gov. [7 June 2017]. （原始内容存档于2020-12-12）.

[3] [3]
fluorotriiodomethane. webbook.nist.gov. [7 June 2017]. （原始内容存档于2019-11-16）.

[4] [4]
Gurvich, L. V.; Veyts, I. Thermodynamic Properties of Individual Substances: Elements and Compounds. CRC Press. September 1, 1990: 185 [2019-03-23]. ISBN 9780891165330. （原始内容存档于2019-09-02）.

[5] [5]
Nozomi Nakayama, Elizabeth E. Ferrenz, Denise R. Ostling, Andrea S. Nichols, Janelle F. Faulk, Christopher R. Arumainayagam. Surface Chemistry and Radiation Chemistry of Trifluoroiodomethane (CF 3 I) on Mo(110). The Journal of Physical Chemistry B. 2004-4, 108 (13): 4080–4085 [2019-03-23]. ISSN 1520-6106. doi:10.1021/jp0310192. （原始内容存档于2021-02-19）（英语）. 请检查|date=中的日期值 (帮助)

[6] [6]
Mahesh Rajappan, Lin L Zhu, Jizhou Wang, Graeme Gardner, Kevin Bu, Huiliang Mai, Madeleine Laupheimer, Yomay Shyur, Nuriesya S Abu Bakar, Samantha K Skinner-Hall, Christina Kim, Jaclyn M Haskins, Christopher R Arumainayagam. The role of low-energy electrons in the high-energy radiolysis of condensed CF 3 I. Journal of Physics: Condensed Matter. 2010-03-03, 22 (8): 084006 [2019-03-23]. ISSN 0953-8984. doi:10.1088/0953-8984/22/8/084006.

[7] [7]
Maslov, P. G.; Maslov, Yu. P. Heats of formation of halogen derivatives of methane and ethylene. Khimiya i Tekhnologiya Topliv i Masel, 1958. 3 (10): 50-55, ISSN 0023-1169.

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