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环戊二烯基三氯化钛

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环戊二烯基三氯化钛
别名 Titanocene trichloride
识别
CAS号 1270-98-0
PubChem 11127785
ChemSpider 11601864
SMILES
性质
化学式 C5H5Cl3Ti
摩尔质量 219.32 g·mol−1
外观 橙色固体
密度 1.768 g/cm3
熔点 210 °C(483 K)
若非注明,所有数据均出自一般条件(25 ℃,100 kPa)下。

环戊二烯基三氯化钛是一种有机钛化合物英语Organotitanium compound,化学式为(C5H5)TiCl3。它是对潮湿敏感的橙色固体,具有钢琴凳(piano stool)几何构型。[1]它可由二氯化二茂钛四氯化钛的反应制得:

(C5H5)2TiCl2 + TiCl4 → 2 (C5H5)TiCl3

它具有亲电性,和醇类可以迅速反应,生成烷氧基配合物。[2]

参考文献

  1. ^ Rossini, A. J.; Mills, R. W.; Briscoe, G. A.; Norton, E. L.; et al. Solid-State Chlorine NMR of Group IV Transition Metal Organometallic Complexes. Journal of the American Chemical Society. 2009, 131 (9): 3317–3330. PMID 19256569. doi:10.1021/ja808390a. 
  2. ^ Andreas Hafner; Rudolf O. Duthaler. Trichloro(cyclopentadienyl)titanium. EEROS. 2001. ISBN 0471936235. doi:10.1002/047084289X.rt202m. 
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环戊二烯基三氯化钛
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