一磷化钛(化学式:TiP)是一种无机化合物,通常为灰色粉末。[1]它是有着高熔点的金属导体。[2]它对水或通常的酸稳定。[1]它的性质和碱金属或碱土金属含P3−的磷化物(如Na3P)相比是不同的,那些磷化物不具备金属性,且会理科水解。[2]一磷化钛被分类为“富金属磷化物”,有着多余的来自金属的离域价电子。[2]
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TiP可以通过TiCl4和PH3的反应制备。[1]
钛的其它磷化物,如Ti3P、[3]Ti2P、[4]Ti7P4、[5]Ti5P3、[6]和Ti4P3[7]等,是已知的。
D.L. Perry S.L. Phillips (1995) Handbook of inorganic compounds CRC Press ISBN 0-8493-8671-3
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Hydrogen absorption in Ti3P Halter U., Mrowietz M., Weiss A Journal of the less-common metals 1986 118 343-348
Structure of Ti2P solved by three-dimensional electron diffraction data collected with the precession technique and high-resolution electron microscopy M. Gemmi, X. D. Zou, S. Hovmöller, A. Migliori, M. Vennström and Y. Andersson Acta Crystallogr. (2003). A59, 117-126 doi:10.1107/S0108767302022559 PMID 12604849
New Phases in the Ti-P and Ti-Cu-P Systems, Carrillo C W., Lundström T Acta Chem.Scand., Series A: (1979), 33, 401-402
Crystal Structure Refinement of Ti5P3 Carrillo C W., Lundström T Acta Chemica Scandinavica, Series A: Physical and Inorganic Chemistry 1980 34 415-419
Phase Relationships in the Ti-P System with some Notes on the Crystal Structures of TiP2 and ZrP2, Snell P.O, Acta Chem. Scand. 1968 22 1942-1952