Cheletropic reaction
Chemical reaction in which a ring is formed/broken by adding/removing a single atom / From Wikipedia, the free encyclopedia
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In organic chemistry, cheletropic reactions, also known as chelotropic reactions,[2] are a type of pericyclic reaction (a chemical reaction that involves a transition state with a cyclic array of atoms and an associated cyclic array of interacting orbitals).[1] Specifically, cheletropic reactions are a subclass of cycloadditions. The key distinguishing feature of cheletropic reactions is that on one of the reagents, both new bonds are being made to the same atom.[3]