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Chemical compound From Wikipedia, the free encyclopedia
Diiron nonacarbonyl is an organometallic compound with the formula Fe2(CO)9. This metal carbonyl is an important reagent in organometallic chemistry and of occasional use in organic synthesis.[3] It is a more reactive source of Fe(0) than Fe(CO)5. This micaceous orange solid is virtually insoluble in all common solvents.
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Names | |||
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IUPAC name
Diiron nonacarbonyl, tri-μ-carbonyl-bis(tricarbonyliron)(Fe—Fe) | |||
Other names
Iron enneacarbonyl | |||
Identifiers | |||
3D model (JSmol) |
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ChemSpider | |||
ECHA InfoCard | 100.035.765 | ||
EC Number |
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PubChem CID |
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CompTox Dashboard (EPA) |
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Properties | |||
Fe2C9O9 | |||
Molar mass | 363.78 g/mol | ||
Appearance | orange crystals | ||
Density | 2.08 g/cm3 | ||
Melting point | decomposes at 100 °C[1] | ||
insoluble, does not react with water[2] | |||
Structure | |||
0 D | |||
Hazards | |||
Occupational safety and health (OHS/OSH): | |||
Main hazards |
Toxic, flammable | ||
GHS labelling: | |||
Danger | |||
Related compounds | |||
Related iron carbonyls |
Iron pentacarbonyl Triiron dodecacarbonyl | ||
Related compounds |
Dimanganese decacarbonyl Dicobalt octacarbonyl | ||
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Following the original method,[4] photolysis of an acetic acid solution of Fe(CO)5 produces Fe2(CO)9 in good yield:[5][6]
Fe2(CO)9 consists of a pair of Fe(CO)3 centers linked by three bridging CO ligands. Although older textbooks show an Fe-Fe bond consistent with the 18 electron rule (8 valence electrons from Fe, two each from the terminal carbonyls, one each from the bridging carbonyls and one from the other Fe atom in the metal-metal bond), theoretical analyses have consistently indicated the absence of a direct Fe-Fe bond:[7] this latter model proposes an Fe-C-Fe three-center-two-electron "banana bond" for one of the bridging carbonyls. The minor isomer has been crystallized together with C60. The iron atoms are equivalent and octahedral molecular geometry. Elucidation of the structure of Fe2(CO)9 proved to be challenging because its low solubility inhibits growth of crystals. The Mößbauer spectrum reveals one quadrupole doublet, consistent with the D3h-symmetric structure.
Fe2(CO)9 is a precursor to compounds of the type Fe(CO)4L and Fe(CO)3(diene). Such syntheses are typically conducted as THF slurries. In these conversions, it is proposed that small amounts of Fe2(CO)9 dissolve according to the following reaction:[8]
Oxidative addition of allyl bromide to diiron nonacarbonyl gives the allyl iron(II) derivative:[9]
Cyclobutadieneiron tricarbonyl is prepared similarly using 3,4-dichlorocyclobutene:[10]
Fe2(CO)9 has also been employed in the synthesis of cyclopentadienones via a net [2+3]-cycloaddition from dibromoketones, known as the Noyori [3+2] reaction.[11]
(Benzylideneacetone)iron tricarbonyl, with the formula (C6H5CH=CHC(O)CH3)Fe(CO)3 is prepared by the reaction of diiron nonacarbonyl with benzylideneacetone.[12] This complex is a source of the Fe(CO)3 fragment.
Low temperature UV/vis photolysis of Fe2(CO)9 yields the Fe2(CO)8 unsaturated complex, producing both CO-bridged and unbridged isomers.[13]
Metal carbonyls are typically treated as if they are highly toxic.[5]
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