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1-Nitroso-2-naphthol

Chemical compound From Wikipedia, the free encyclopedia

1-Nitroso-2-naphthol
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1-Nitroso-2-naphthol is an organic compound with the formula C10H6(NO)OH. It is one of several possible nitrosonaphthols, and the most studied for applications as an indicator and a dye.[2]

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Synthesis and reactions

1-Nitroso-2-naphthol can be prepared by treatment of 2-naphthol with nitrous acid:[3]

C10H7OH + HNO2 → C10H6(NO)OH + H2O

Its conjugate base forms deeply colored complexes with iron(II) and cobalt(II), complexes [M(C10H6(NO)O)3]2-.[4] The deep colors of these complexes results from the delocalized bonding within each five-membered chelate ring. These species can be classified as nitroso complexes.

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See also

  • Naphthol Green B, the iron complex of a sulfonated derivative of 1-nitroso-2-naphthol

References

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