Ammonium tetrafluoroborate (or ammonium fluoroborate ) is an inorganic salt composed of the ammonium cation and the tetrafluoroborate anion, with the chemical formula NH4 BF4 . When heated to decomposition, ammonium tetrafluoroborate releases toxic fumes of hydrogen fluoride , nitrogen oxides , and ammonia .[ 4]
Quick Facts Names, Identifiers ...
Ammonium tetrafluoroborate
Names
IUPAC name
Ammonium tetrafluoroborate
Other names
Identifiers
ChemSpider
ECHA InfoCard
100.034.106
EC Number
UNII
UN number
1759 3077
InChI=1S/BF4.H3N/c2-1(3,4)5;/h;1H3/q-1;/p+1
Key: PDTKOBRZPAIMRD-UHFFFAOYSA-O
Properties
NH4 BF4
Molar mass
104.85 g/mol
Appearance
Colorless to white crystals[ 1]
Density
1.871 g/cm3
Melting point
220-230 °C (Sublimes)[ 2]
Boiling point
N/A
3.09 g/100 ml (-1.0 °C) 5.26 g/100 ml (-1.5 °C) 10.85 g/100 ml (-2.7 °C) 12.20 g/100 ml (0 °C) 25 g/100 ml (16 °C) 25.83 g/100 ml (25 °C) 44.09 g/100 ml (50 °C) 67.50 g/100 ml (75 °C) 98.93 g/100 ml (100 °C) 113.7 g/100 ml (108.5 °C)
Solubility
Ammonium hydroxide [ 3]
Hazards
Occupational safety and health (OHS/OSH):
Main hazards
Corrosive, irritant, toxic if ingested
GHS labelling :
Warning
H290 , H314 , H315 , H319 , H335
P234 , P260 , P261 , P264 , P271 , P280 , P301+P330+P331 , P302+P352 , P303+P361+P353 , P304+P340 , P305+P351+P338 , P310 , P312 , P321 , P332+P313 , P337+P313 , P362 , P363 , P390 , P403+P233 , P404 , P405 , P501
Safety data sheet (SDS)
Related compounds
Tetrafluoroborate
Ammonium
Except where otherwise noted, data are given for materials in their
standard state (at 25
°C [77
°F], 100
kPa).
Close