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Barium iodide

Chemical compound From Wikipedia, the free encyclopedia

Barium iodide
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Barium iodide is an inorganic compound with the formula BaI2. The compound exists as an anhydrous and a hydrate (BaI2(H2O)2), both of which are white solids. When heated, hydrated barium iodide converts to the anhydrous salt. The hydrated form is freely soluble in water, ethanol, and acetone.

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Structure

The structure of the anhydrous form resembles that of lead(II) chloride with each Ba center bound to nine iodide ligands[2] and has a crystalline packing structure that is quite similar to BaCl2.[3]

Reactions

Anhydrous BaI2 can be prepared by treating Ba metal with 1,2-diiodoethane in ether.[4]

BaI2 reacts with alkyl potassium compounds to form organobarium compounds.[5]

BaI2 can be reduced with lithium biphenyl, to give a highly active form of barium metal.[6]

Safety

Like other soluble salts of barium, barium iodide is toxic.

References

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