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Barium iodide
Chemical compound From Wikipedia, the free encyclopedia
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Barium iodide is an inorganic compound with the formula BaI2. The compound exists as an anhydrous and a hydrate (BaI2(H2O)2), both of which are white solids. When heated, hydrated barium iodide converts to the anhydrous salt. The hydrated form is freely soluble in water, ethanol, and acetone.
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Structure
The structure of the anhydrous form resembles that of lead(II) chloride with each Ba center bound to nine iodide ligands[2] and has a crystalline packing structure that is quite similar to BaCl2.[3]
Reactions
Anhydrous BaI2 can be prepared by treating Ba metal with 1,2-diiodoethane in ether.[4]
BaI2 reacts with alkyl potassium compounds to form organobarium compounds.[5]
BaI2 can be reduced with lithium biphenyl, to give a highly active form of barium metal.[6]
Safety
Like other soluble salts of barium, barium iodide is toxic.
References
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