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Cacodyl oxide

Chemical compound From Wikipedia, the free encyclopedia

Cacodyl oxide
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Cacodyl oxide is a chemical compound of the formula [(CH3)2As]2O. This organoarsenic compound is primarily of historical significance since it is sometimes considered to be the first organometallic compound synthesized in relatively pure form.[1][2]

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"Cadet's fuming liquid", which is composed of cacodyl and cacodyl oxide, was originally synthesized by heating potassium acetate with arsenic trioxide. It has a disagreeable odor and is toxic.

The molecular structure of [Ph2As]2O (Ph = phenyl), the tetraphenyl analogue of cacodyl oxide, has been established by X-ray crystallography.[3]

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