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Cerium(IV) fluoride

Chemical compound From Wikipedia, the free encyclopedia

Cerium(IV) fluoride
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Cerium(IV) fluoride is an inorganic compound with a chemical formula CeF4. It is a strong oxidant that appears as a white crystalline material. Cerium(IV) fluoride has an anhydrous form and a monohydrate form.[2]

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Production and properties

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Cerium(IV) fluoride can be produced by fluorinating cerium(III) fluoride or cerium dioxide with fluorine gas at 500 °C[3]

Its hydrated form (CeF4·xH2O, x≤1) can be produced by reacting 40% hydrofluoric acid and cerium(IV) sulfate solution at 90°C.[4]

Cerium(IV) fluoride can dissolve in DMSO, and react to form the coordination complex [CeF4(DMSO)2].[4]

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References

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