Dilithium

This article is about the real substance. For other uses, see Dilithium (disambiguation).

Dilithium, Li₂, is a strongly electrophilic, diatomic molecule comprising two lithium atoms covalently bonded together. Li₂ has been observed in the gas phase. It has a bond order of 1, an internuclear separation of 267.3 pm and a bond energy of 102 kJ/mol or 1.06 eV in each bond.^[1] The electron configuration of Li₂ may be written as σ².^{[citation needed]}

Dilithium

Wireframe model of dilithium
Spacefill model of dilithium
Names
IUPAC name Dilithium(Li—Li)[citation needed]
Identifiers
CAS Number	14452-59-6 N
3D model (JSmol)	Interactive image
ChemSpider	123254 Y
PubChem CID	139759
CompTox Dashboard (EPA)	DTXSID90162747
InChI InChI=1S/2Li Y Key: SMBQBQBNOXIFSF-UHFFFAOYSA-N Y
SMILES [Li][Li]
Properties
Chemical formula	Li2
Molar mass	13.88 g·mol−1
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). N verify (what is YN ?) Infobox references

Being the third-lightest stable^{[citation needed]} neutral homonuclear diatomic molecule (after dihydrogen and dihelium), dilithium is an extremely important model system for studying fundamentals of physics, chemistry, and electronic structure theory.

It is the most thoroughly characterized compound in terms of the accuracy and completeness of the empirical potential energy curves of its electronic states. Analytic empirical potential energy curves have been constructed for the X-state,^[2] a-state,^[3] A-state,^[4] c-state,^[5] B-state,^[6] 2d-state,^[7] l-state,^[7] E-state,^[8] and the F-state.^{[clarification needed][9]} The most reliable of these potential energy curves are of the Morse/Long-range variety (see entries in the table below).^{[2][3][6][4][5]}

Li₂ potentials are often used to extract atomic properties. For example, the C₃ value for atomic lithium extracted from the A-state potential of Li₂ by Le Roy et al. in ^[2] is more precise than any previously measured atomic oscillator strength.^[10] This lithium oscillator strength is related to the radiative lifetime of atomic lithium and is used as a benchmark for atomic clocks and measurements of fundamental constants.

Electronic state	Spectroscopic symbol[clarification needed]	Term symbol	Bond length (pm)		Dissociation energy (cm−1)		Bound vibrational levels	References
1 (Ground)	X	11Σg+	267	.298 74(19)[2]	8 516	.780 0(23)[2]	39[2]	[2]
2	a	13Σu+	417	.000 6(32)[3]	333	.779 5(62)[3]	11[3]	[3]
3	b	13Πu						[7]
4	A	11Σg+	310	.792 88(36)[2]	9 353	.179 5 (28)[2]	118[2]	[2]
5	c	13Σg+	306	.543 6(16)[3]	7 093	.492 6(86)[3]	104[3]
6	B	11Πu	293	.617 142(310)[6]	2 984	.444[6]	118[6]
7	E	3(?)1Σg+						[8]

See also

• Morse/Long-range potential
• Molecular orbital diagram § Dilithium
• Dilithium (Star Trek)