Top Qs
Timeline
Chat
Perspective

Dimethyl sulfite

Chemical compound From Wikipedia, the free encyclopedia

Dimethyl sulfite
Remove ads

Dimethyl sulfite is a sulfite ester with the chemical formula (CH3O)2SO.

Quick Facts Names, Identifiers ...

Dimethyl sulfite is used as an additive in some polymers to prevent oxidation.[2] It is also a potentially useful high energy battery electrolyte solvent.[3]

Remove ads

Structure and conformation

The dimethyl sulfite molecule can adopt several conformations. The most stable is the GG conformer.[1] Each C–O bond is gauche to the S=O bond, depicted below.

Thumb

Preparation

Dimethyl sulfite is prepared from a 1:2 ratio of thionyl chloride and methanol.[4] The reaction can be catalyzed by tertiary amine bases and likely proceeds via the chlorosulfinate (MeOS(O)Cl),[5] this intermediate will exist only fleetingly in the presence of methanol and as such its decomposition to methyl chloride and sulfur dioxide (via the slower SNi mechanism) is not observed to any great extent.

SOCl2 + 2 CH3OH → (CH3O)2SO + 2 HCl
Remove ads

See also

References

Loading related searches...

Wikiwand - on

Seamless Wikipedia browsing. On steroids.

Remove ads