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Europium(III) oxalate

Chemical compound From Wikipedia, the free encyclopedia

Europium(III) oxalate
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Europium(III) oxalate (Eu2(C2O4)3) is a chemical compound of europium and oxalic acid. There are different hydrates including the decahydrate, hexahydrate and tetrahydrate.[1] Europium(II) oxalate is also known.[3]

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Preparation

An excess of oxalate is added to a hot solution of Eu3+ cations. The resulting precipitate of Eu2(C2O4)3  10H2O is dried in a desiccator.[4]

Properties

Europium(III) oxide (Eu2O3) can be prepared by calcining europium(III) oxalate.[5]

The dehydration of Eu2(C2O4)3 · 10H2O occurs below 200 °C:[1]

Eu2(C2O4)3·10H2O → Eu2(C2O4)3·6H2O → Eu2(C2O4)3·4H2O → Eu2(C2O4)3

The decomposition of this compound takes place in two stages, the first at 350 °C and the second at about 620 °C.[1][6]

Eu2(C2O4)3 → Eu2[CO3]3 + 3 CO → Eu2O3 + 3 CO2 + 3 CO

In the Mössbauer spectrum, Eu2(C2O4)3 · 10H2O shows an isomer shift of +0,26 mm/s with a line width of 2,38 mm/s, in reference to EuF3.[4][7] The Debye temperature of Eu2(C2O4)3 is 166±15 K.[8]

Eu2(C2O4)3 · 10H2O crystallizes monoclinically in the space group of P21/c (space group no. 14) with the lattice parameters a = 1098, b = 961, c = 1004 pm and β = 114.2° with four formula units per unit cell.[9]

Nanoparticles show a line emission when excited by a light source of 393 nm, the transitions 5D07F1 (592 nm) and 5D07F2 (616 nm) can then be found in the spectrum. This can be used as a red phosphor for white LEDs.[10]

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References

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