Hexaoxygen difluoride

Chemical compound From Wikipedia, the free encyclopedia

Hexaoxygen difluoride is a binary inorganic compound of fluorine and oxygen with the chemical formula O6F2.[1][2] The compound is one of many known oxygen fluorides.[3]

Quick Facts Identifiers, Properties ...
Hexaoxygen difluoride
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Identifiers
3D model (JSmol)
  • InChI=1S/F2O6/c1-3-5-7-8-6-4-2
    Key: PHJAHINOOJESQK-UHFFFAOYSA-N
  • FOOOOOOF
Properties
F2O6
Molar mass 133.991 g·mol−1
Appearance dark-brown solid at 60 K
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Synthesis

The compound can be prepared by electric discharges through the F2O2 mixture of the certain molar ratio at 60 to 77 K. The ratio is predicted to be 6:2.[4]

Physical properties

Hexaoxygen difluoride is an oxidizing agent. At 60 K, the compound looks like a dark-brown crystalline solid. If slowly warmed, it decomposes to lower oxygen fluorides and ozone. If quickly warmed to 90 K, it explodes, creating O2 and F2.[4]

References

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