Iodide hydride

Iodide hydrides are mixed anion compounds containing hydride and iodide anions. Many iodide hydrides are cluster compounds, containing a hydrogen atom in a core, surrounded by a layer of metal atoms, encased in a shell of iodide.

List

formula	system	space group	unit cell Å	volume	density	comment	reference
(DippNacnac)Mg(μ-H)(μ-I)Mg(MesNacnac)							[1]
KHI							[2][3]
[LZnI(η2-H)]2 (L=1,3-bis(2,6-diisopropylphenyl)inidazole-2-ylidine							[4]
Sr2H3I	trigonal	P3m1	a = 4.260 c = 7.749 Z=1	121.77	4.16	transparent	[5]
YIH			C=31.033			metallic	[6]
YIH2		P3m1	a = 3.8579, c = 10.997			light green	[6]
Nb6I11H		D10/2h	a = 11.317; b = 15.471 ; c = 13.431				[7]
Nb6I11H		Im3m	a = 11.317; b = 15.471 ; c = 13.431			black	[7]
Nb6(H)I9S	triclinic	P1	a = 10.340, b = 11.554, c = 10.181, α = 104.31°, β = 113.50°, γ = 105.48° Z=2				[8][9]
HCsNb6I11							[10]
Ba2H3I	trigonal	P3m1	a= 4.519 c= 8.1184			transparent	[11]
Ba5H2I4O2	orthorhombic	Cmcm	a =17.210, b = 14.525 c = 6.3903 Z=4	1597.44	5.11	transparent	[5]
LaI2H	hexagonal	P63/mmc	a=4.2158 c=15.508				[12][13]
Cel2H0.90		R3m					[14]
Cel2D0.96		R3m					[14]
NdI2H							[15]
GdI2H0.97		R3m				transparent blue	[16]
Gd2ICH0.73		P63mc	a=3.8128 C=14.844 Z=2		8.071		[17]
Eu2H3I						dark red	[18]
Eu5H2O2I4	orthorhombic	Cmcm	a = 16.3697, b = 13.6954, c = 6.0436, Z = 4			dark red	[18]
Tb2ICH							[17]
DyI2H							[15]
[(η5-C5H5)W(NO)IH]2							[19]
(η5-C5H5)W(NO)I(H)(P(OPh)3)
Ir(η2-H2)(H)2I(PiPr3)2							[20][21]
Ir(η2-H2)(H)2I(PiPr3)2•C10H8	triclinic	P1	a=7.999 b=13.981 c=14.561 α=82.49° β=84.39° γ=71.70° Z=2			15K	[21]