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Lanthanum nitride
Chemical compound From Wikipedia, the free encyclopedia
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Lanthanum nitride is a binary inorganic compound of lanthanum and nitride with the chemical formula LaN.[1][2]
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Preparation
Lanthanum nitride can be prepared from the reaction of nitrogen and lanthanum trihydride:
- 2LaH3 + N2 → 2LaN + 3H2
It can also be prepared from the reaction of ammonia and lanthanum trihydride:[3]
- LaH3 + NH3 → LaN + 3H2
The reaction of nitrogen and lanthanum amalgam can also work:[4]
- La + 1/2 N2 → LaN
(1000 - 1400 C)
Ammonia is more reactive than N2 gas, so the synthesis works at lower temperatures:
La + NH3 -> LaN + 3/2 H2 (700 C)
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Physical properties
Lanthanum nitride forms black powder that is insoluble in water.[1] Their crystals are of the cubic system with the Fm3m space group.[5]
It is paramagnetic.
Chemical properties
Lanthanum nitride reacts with water and moisture from the air:[6]
- LaN + 3H2O → La(OH)3 + NH3
It reacts with acids:
- LaN + 4HCl → LaCl3 + NH4Cl
Uses
Gerbicidum. LaN is used as a LED material, magnetic material, semiconductor, refractory material, dyes, catalyst.[7]
References
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