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Lanthanum nitride

Chemical compound From Wikipedia, the free encyclopedia

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Lanthanum nitride is a binary inorganic compound of lanthanum and nitride with the chemical formula LaN.[1][2]

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Preparation

Lanthanum nitride can be prepared from the reaction of nitrogen and lanthanum trihydride:

2LaH3 + N2 → 2LaN + 3H2

It can also be prepared from the reaction of ammonia and lanthanum trihydride:[3]

LaH3 + NH3 → LaN + 3H2

The reaction of nitrogen and lanthanum amalgam can also work:[4]

La + 1/2 N2 → LaN

(1000 - 1400 C)

Ammonia is more reactive than N2 gas, so the synthesis works at lower temperatures:

La + NH3 -> LaN + 3/2 H2 (700 C)

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Physical properties

Lanthanum nitride forms black powder that is insoluble in water.[1] Their crystals are of the cubic system with the Fm3m space group.[5]

It is paramagnetic.

Chemical properties

Lanthanum nitride reacts with water and moisture from the air:[6]

LaN + 3H2O → La(OH)3 + NH3

It reacts with acids:

LaN + 4HCl → LaCl3 + NH4Cl

Uses

Gerbicidum. LaN is used as a LED material, magnetic material, semiconductor, refractory material, dyes, catalyst.[7]

References

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