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Lanthanum strontium cobalt ferrite

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Lanthanum strontium cobalt ferrite (LSCF), also called lanthanum strontium cobaltite ferrite is a specific ceramic oxide derived from lanthanum cobaltite of the ferrite group. It is a phase containing lanthanum(III) oxide, strontium oxide, cobalt oxide and iron oxide with the formula La
x
Sr
1−x
Co
y
Fe
1−y
O
3
, where 0.1≤x≤0.4 and 0.2≤y≤0.8.[1]

It is black in color and crystallizes in a distorted hexagonal perovskite structure.[2] LSCF undergoes phase transformations at various temperatures depending on the composition. This material is a mixed ionic electronic conductor with comparatively high electronic conductivity (200+ S/cm) and good ionic conductivity (0.2 S/cm).[3] It is typically non-stoichiometric and can be reduced further at high temperature in low oxygen partial pressures or in the presence of a reducing agent such as carbon.[4]

LSCF is being investigated as a material for intermediate temperature solid oxide fuel cell cathodes and, potentially as a direct carbon fuel cell anode.[2]

LSCF is also investigated as a membrane material for separation of oxygen from air, for use in e.g. cleaner burning power plants.[5]

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See also

  • Lanthanum strontium manganite (LSM)
  • Lanthanum strontium ferrite (LSF)
  • Lanthanum calcium manganite (LCM)
  • Lanthanum strontium chromite (LSC)
  • Lanthanum strontium gallate magnesite (LSGM)

References

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