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Methanol (data page)

Chemical data page From Wikipedia, the free encyclopedia

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This page provides supplementary chemical data on methanol.

Safety Data Sheet

The handling of this chemical may incur notable safety precautions. It is highly recommended that you seek the Safety Datasheet (SDS) for this chemical from a reliable source such as SIRI, and follow its directions. SDS is available at MSDS, J.T. Baker and Loba Chemie

Structure and properties

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Thermodynamic properties

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Spectral data

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Vapor pressure of liquid

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P in mm Hg 1104090400760152038007600152003040045600
T in °C −44.0−16.25.021.249.964.784.0112.5138.0167.8203.5224.0

Table data obtained from CRC Handbook of Chemistry and Physics 44th ed

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Methanol vapor pressure vs. temperature. Uses Antoine's equation: from Lange's Handbook of Chemistry 10th ed.
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Log10 of methanol vapor pressure vs. temperature. Uses Antoine's equation: from Lange's Handbook of Chemistry 10th ed.

Here is a similar formula from the 67th edition of the CRC handbook. Note that the form of this formula as given is a fit to the Clausius–Clapeyron equation, which is a good theoretical starting point for calculating saturation vapor pressures:

log10(P) = −(0.05223)a/T + b, where P is in mmHg, T is in kelvins, a = 38324, and b = 8.8017.
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Properties of aqueous methanol solutions

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Data obtained from Lange's Handbook of Chemistry, 10th ed. and CRC Handbook of Chemistry and Physics 44th ed. The annotation, d a°C/b°C, indicates density of solution at temperature a divided by density of pure water at temperature b known as specific gravity. When temperature b is 4 °C, density of water is 0.999972 g/mL.

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Distillation data

More information BPtemp. °C, % by mole methanol ...
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References

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