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Phosphorus tetroxide

Chemical compound From Wikipedia, the free encyclopedia

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Diphosphorus tetroxide, or phosphorus tetroxide is an inorganic compound of phosphorus and oxygen. It has the empirical chemical formula P2O4. Solid phosphorus tetroxide (also referred to as phosphorus(III,V)-oxide) consists of variable mixtures of the mixed-valence oxides P4O7, P4O8 and P4O9.[1][2][3]

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Preparation

Phosphorus tetroxide can be produced by thermal decomposition of phosphorus trioxide, which disproportionates above 210 °C to form phosphorus tetroxide, with elemental phosphorus as a byproduct:

8 P2O3 ⇌ P4 + 6 P2O4

In addition, phosphorus trioxide can be converted into phosphorus tetroxide by controlled oxidation with oxygen in carbon tetrachloride solution.[4][5][6]

Careful reduction of phosphorus pentoxide with red phosphorus at 450-525 °C also produces phosphorus tetroxide.

References

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