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Potassium carbonate

Chemical compound From Wikipedia, the free encyclopedia

Potassium carbonate
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Potassium carbonate is the inorganic compound with the formula K2CO3. It is a white salt, which is soluble in water and forms a strongly alkaline solution. It is deliquescent, often appearing as a damp or wet solid. Potassium carbonate is mainly used in the production of soap and glass.[3] Commonly, it can be found as the result of leakage of alkaline batteries.[4] Potassium carbonate is a potassium salt of carbonic acid. This salt consists of potassium cations K+ and carbonate anions CO2−3, and is therefore an alkali metal carbonate.

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History

Potassium carbonate is the primary component of potash and the more refined pearl ash or salt of tartar. Historically, pearl ash was created by baking potash in a kiln to remove impurities. The fine, white powder remaining was the pearl ash. The first patent issued by the US Patent Office was awarded to Samuel Hopkins in 1790 for an improved method of making potash and pearl ash.[5]

In late 18th-century North America, before the development of baking powder, pearl ash was used as a leavening agent for quick breads.[6][7]

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Production

The modern commercial production of potassium carbonate is by reaction of potassium hydroxide with carbon dioxide:[3]

2 KOH + CO2 → K2CO3 + H2O

From the solution crystallizes the sesquihydrate K2CO3·1.5H2O ("potash hydrate"). Heating this solid above 200 °C (392 °F) gives the anhydrous salt. In an alternative method, potassium chloride is treated with carbon dioxide in the presence of an organic amine to give potassium bicarbonate, which is then calcined:

2 KHCO3 → K2CO3 + H2O + CO2
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