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Sodium cyanate
Chemical compound From Wikipedia, the free encyclopedia
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Sodium cyanate is the inorganic compound with the formula NaOCN. A white solid, it is the sodium salt of the cyanate anion.
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Structure
The anion is described by two resonance structures: N≡C−O− and −N=C=O
The salt adopts a body centered rhombohedral crystal lattice structure (trigonal crystal system) at room temperature.[1]
Preparation
Sodium cyanate is prepared industrially by the reaction of urea with sodium carbonate at elevated temperature.
- 2OC(NH2)2 + Na2CO3 → 2Na(NCO) + CO2 + 2NH3 + H2O
Sodium allophanate is observed as an intermediate:[2]
- H2NC(O)NHCO2Na → NaOCN + NH3 + CO2
It can also be prepared in the laboratory by oxidation of a cyanide in aqueous solution by a mild oxidizing agent such as lead oxide.[3]
Uses and reactions
The main use of sodium cyanate is for steel hardening.[2]
Sodium cyanate is used to produce cyanic acid, often in situ:
- NaOCN + HCl → HOCN + NaCl
This approach is exploited for condensation with amines to give unsymmetrical ureas:
- HOCN + RNH2 → RNHC(O)NH2
Such urea derivatives have a range of biological activity.[4]
See also
References
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