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Stannate

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In chemistry, the term stannate or tinnate refers to compounds of tin (Sn). Stannic acid (Sn(OH)4), the formal precursor to stannates, does not exist and is actually a hydrate of SnO2.[1] The term is also used in naming conventions as a suffix; for example the hexachlorostannate ion is SnCl2−
6
.

In materials science, two kinds of tin oxyanions are distinguished:

  • orthostannates contain discrete SnO4−
    4
    units (e.g. K4SnO4) or have a spinel structure (e.g. Mg2SnO4)
  • metastannates with a stoichiometry MIISnO3, MI
    2
    SnO3 which may contain polymeric anions or may be sometimes better described as mixed oxides

These materials are semiconductors.[2]

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