Boyland–Sims oxidation

Boyland–Sims oxidation jẹ́ ìdàpapọ̀ ṣiṣẹ́ kẹ́míkà ti àwọn aniline pẹ̀lú alkaline potassium persulfate, tí ó jẹ́ pé lẹ́yìn dídomi sí rẹ̀ ó maa di  ortho-hydroxyl àwọn aniline.^[1][2][3]

The Boyland-Sims oxidation

 Ortho-isomer ló maa ń jẹyọ. Síbẹ̀síbẹ̀, para-sulfate maa jẹyọ ní bíntí pẹ̀lú àwọn analine kan .^[4]

Ètò ìdàpọ̀ ṣiṣẹ́

Behrman ti fihàn pé oun àkọ́kọ́ tí a maa rí nínú  Boyland–Sims oxidation ni jíjẹyọ arylhydroxylamine-O-sulfate (2).^[5] Àtúntò zwitterionic yìí maa jẹ́ kí a rí ortho- sulfate (5), tí a maa domisí lati lè rí ortho-hydroxyl aniline.

The mechanism of the Boyland-Sims oxidation

Ìwé àkàsíwájú si

• Behrman, Edward J. (2014). "On the Mechanism of the Boyland-Sims Oxidation". Progress in Reaction Kinetics and Mechanism (Science Reviews 2000 Ltd) 39 (3): 308–310. doi:10.3184/146867814X14062204626705. Archived from the original on 2016-07-16. https://web.archive.org/web/20160716153749/http://www.sciencereviews2000.co.uk/view/journal/progress-in-reaction-kinetics-and-mechanism.

Tún wo

• Elbs persulfate oxidation