2-Bromoanisole
Chemical compound / From Wikipedia, the free encyclopedia
2-Bromoanisole is an organobromide with the formula BrC6H4OCH3. A colorless liquid, it is one of three isomers of bromoanisole, the others being 3-bromoanisole and 4-bromoanisole. It is a standard coupling partner in metal catalyzed coupling reactions. These reactions include Heck reactions, Buchwald-Hartwig coupling,[1] Suzuki couplings, and Ullmann condensations.[2] The corresponding Grignard reagent readily forms. It is a precursor to o-anisaldehyde.[3][4]
Quick Facts Names, Identifiers ...
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Preferred IUPAC name
1-Bromo-2-methoxybenzene | |
Identifiers | |
3D model (JSmol) |
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ChemSpider | |
ECHA InfoCard | 100.008.570 |
EC Number |
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PubChem CID |
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UNII | |
CompTox Dashboard (EPA) |
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Properties | |
C7H7BrO | |
Molar mass | 187.036 g·mol−1 |
Appearance | Colorless liquid |
Melting point | 2.5 °C (36.5 °F; 275.6 K) |
Boiling point | 216 °C (421 °F; 489 K) |
Hazards | |
GHS labelling: | |
Warning | |
H411 | |
P273, P391, P501 | |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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