Electron affinity (data page)

Chemical data page From Wikipedia, the free encyclopedia

This page deals with the electron affinity as a property of isolated atoms or molecules (i.e. in the gas phase). Solid state electron affinities are not listed here.

Elements

Summarize
Perspective

Electron affinity can be defined in two equivalent ways. First, as the energy that is released by adding an electron to an isolated gaseous atom. The second (reverse) definition is that electron affinity is the energy required to remove an electron from a singly charged gaseous negative ion. The latter can be regarded as the ionization energy of the −1 ion or the zeroth ionization energy.[1] Either convention can be used.[2]

Negative electron affinities can be used in those cases where electron capture requires energy, i.e. when capture can occur only if the impinging electron has a kinetic energy large enough to excite a resonance of the atom-plus-electron system. Conversely electron removal from the anion formed in this way releases energy, which is carried out by the freed electron as kinetic energy. Negative ions formed in these cases are always unstable. They may have lifetimes of the order of microseconds to milliseconds, and invariably autodetach after some time.

† A quantum offset of the velocity imaging-based measurements was revealed in 2025,[3] which could make a revision of all electron affinities marked with a dagger necessary. The value of the downward correction to be applied is determined by the intensity of the electric field that was used in the experiment, which was not published with the original measurements, but can be estimated to be of the order of −20 μeV.


More information Z, Element ...
ZElementNameElectron affinity (eV)Electron affinity (kJ/mol)References
1 1H Hydrogen0.754 195(19)72.769(2)[4]
1 2H Deuterium0.754 67(4)72.814(4)[5]
2HeHelium−0.5(2)−48(20)est.[6]
3LiLithium0.618 049(22)59.632 6(21)[7]
4BeBeryllium−0.5(2)−48(20)est.[6]
5BBoron0.279 723(25)26.989(3)[8]
6 12C Carbon1.262 122 6(11)121.776 3(1)[9]
6 13C Carbon1.262 113 6(12)121.775 5(2)[9]
7NNitrogen−0.07−6.8[6]
8 16O Oxygen1.461 112 97(9)140.975 970(9)[10]
8 17O Oxygen1.461 108(4)140.975 5(3)[11]
8 18O Oxygen1.461 105(3)140.975 2(3)[11]
9FFluorine3.401 189 8(24)328.164 9(3)[12][13]
10NeNeon−1.2(2)−116(19)est.[6]
11NaSodium0.547 926(25)52.867(3)[14]
12MgMagnesium−0.4(2)−40(19)est.[6]
13AlAluminium0.432 83(5)41.762(5)[15]
14SiSilicon1.389 521 2(8)134.068 4(1)[16]
15PPhosphorus0.746 609(11)72.037(1)[17]
16 32S Sulfur2.077 104 2(6)200.410 1(1)[16]
16 34S Sulfur2.077 104 5(12)200.410 1(2)[18]
17ClChlorine3.612 725(28)348.575(3)[19]
18ArArgon−1.0(2)−96(20)est.[6]
19KPotassium0.501 459(13)48.383(2)[20]
20CaCalcium0.024 55(10)2.37(1)[21]
21ScScandium0.179 380(23)17.307 6(22)[22]
22TiTitanium0.075 54(5)7.289(5)[23]
23VVanadium0.527 66(20)50.911(20)[24]
24CrChromium0.675 928(27)65.217 2(26)[22]
25MnManganese−0.5(2)−50(19)est.[6]
26FeIron0.153 236(35)14.785(4)[25]
27CoCobalt0.662 255(47)63.897 9(45)[26]
28NiNickel1.157 16(12)111.65(2)[27]
29CuCopper1.235 78(4)119.235(4)[28]
30ZnZinc−0.6(2)−58(20)est.[6]
31GaGallium0.301 166(15)29.058 1(15)[29]
32GeGermanium1.232 676 4(13)118.935 2(2)[30]
3375AsArsenic0.804 486(3)77.621 1(3)[3]
34SeSelenium2.020 604 7(12)194.958 7(2)[31]
35BrBromine3.363 588(3)324.536 9(3)[12]
36KrKrypton−1.0(2)−96(20)est.[6]
37RbRubidium0.485 916(21)46.884(3)[32]
38SrStrontium0.052 06(6)5.023(6)[33]
39YYttrium0.311 29(22)30.035(21)[22]
40ZrZirconium0.433 28(9)41.806(9)[34]
41NbNiobium0.917 40(7)88.516(7)[35]
42MoMolybdenum0.747 23(8)72.097(8)[22]
43TcTechnetium0.55(20)53(20)est.[36]
44RuRuthenium1.046 27(2)100.950(3)[22]
45RhRhodium1.142 89(20)110.27(2)[27]
46PdPalladium0.562 14(12)54.24(2)[27]
47AgSilver1.304 47(3)125.862(3)[28]
48CdCadmium−0.7(2)−68(20)est.[6]
49InIndium0.29928.9[37]
50SnTin1.112 070(2)107.298 4(3)[38]
51SbAntimony1.047 401(19)101.059(2)[39]
52TeTellurium1.970 875(7)190.161(1)[40]
53127IIodine3.059 046 5(37)295.153 1(4)[41]
53128IIodine3.059 052(38)295.154(4)[42]
54XeXenon−0.8(2)−77(20)est.[6]
55CsCaesium0.4715983(38)45.5023(4)[43]
56BaBarium0.144 62(6)13.954(6)[44]
57LaLanthanum0.557 546(20)53.795(2)[45]
58CeCerium0.600 160(27)57.906 7(26)[46]
59PrPraseodymium0.109 23(46)10.539(45)[47]
60NdNeodymium0.097 49(33)9.406(32)[47]
61PmPromethium0.12912.45[48]
62SmSamarium0.16215.63[48]
63EuEuropium0.116(13)11.2(13)[49]
64GdGadolinium0.212(30)20.5(29)[22]
65TbTerbium0.131 31(80)12.670(77)[47]
66DyDysprosium0.015(3)1.45(30)[50]
67HoHolmium0.33832.61[48]
68ErErbium0.31230.10[48]
69TmThulium1.029(22)99(3)[51]
70YbYtterbium−0.02−1.93est.[36]
71LuLutetium0.238 8(7)23.04(7)[52]
72HfHafnium0.178 0(7)17.18(7)[53]
73TaTantalum0.328 859(23)31.730 1(22)[22]
74WTungsten0.816 500(82)78.780 3(80)[22]
75ReRhenium0.060 396(64)5.827 3(62)[54]
76OsOsmium1.077 661(24)103.978 5(24)[22]
77IrIridium1.564 057(12)150.908 6(12)[55]
78PtPlatinum2.125 10(5)205.041(5)[56]
79AuGold2.308 610(25)222.747(3)[57]
80HgMercury−0.5(2)−48(20)est.[6]
81TlThallium0.320 053(19)30.880 4(19)[58]
82PbLead0.356 721(2)34.418 3(3)[59]
83BiBismuth0.942 362(13)90.924(2)[60]
84PoPolonium1.40(7)136(7)calc.[61]
85AtAstatine2.415 78(7)233.087(8)[62]
86RnRadon−0.7(2)−68(20)est.[6]
87FrFrancium0.48646.89est.[63][36]
88RaRadium0.109.648 5est.[64][36]
89AcActinium0.3533.77est.[36]
90ThThorium0.607 69(6)58.633(6)[65]
91PaProtactinium0.5553.03est.[66]
92UUranium0.314 97(9)30.390(9)[67]
93NpNeptunium0.4845.85est.[66]
94PuPlutonium−0.50−48.33est.[66]
95AmAmericium0.109.93est.[66]
96CmCurium0.2827.17est.[66]
97BkBerkelium−1.72−165.24est.[66]
98CfCalifornium−1.01−97.31est.[66]
99EsEinsteinium−0.30−28.60est.[66]
100FmFermium0.3533.96est.[66]
101MdMendelevium0.9893.91est.[66]
102NoNobelium−2.33−223.22est.[66]
103LrLawrencium−0.31−30.04est.[66]
111RgRoentgenium1.565151.0calc.[68]
113NhNihonium0.6966.6calc.[69]
115McMoscovium0.36635.3calc.[69]
116LvLivermorium0.77674.9calc.[69]
117TsTennessine1.719165.9calc.[69]
118OgOganesson0.080(6)7.72(58)calc.[70]
119UueUnunennium0.66263.87calc.[63]
120UbnUnbinilium0.0212.03calc.[71]
121UbuUnbiunium0.5755calc.[36]
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Molecules

Summarize
Perspective

The electron affinities Eea of some molecules are given in the table below, from the lightest to the heaviest. Many more have been listed by Rienstra-Kiracofe et al. (2002). The electron affinities of the radicals OH and SH are the most precisely known of all molecular electron affinities.

More information Molecule, Name ...
MoleculeNameEea (eV)Eea (kJ/mol)References
Diatomics
16OHHydroxyl1.827 6488(11)176.3413(2)Goldfarb et al. (2005)
16OD1.825 53(4)176.137(5)Schulz et al. (1982)
C2Dicarbon3.269(6)315.4(6)Ervin & Lineberger (1991)
BOBoron oxide2.508(8)242.0(8)Wenthold et al. (1997)
NONitric oxide0.026(5)2.5(5)Travers, Cowles & Ellison (1989)
O2Dioxygen0.450(2)43.42(20)Schiedt & Weinkauf (1995)
32SHSulfhydryl2.314 7283(17)223.3373(2)Chaibi et al. (2006)
F2Difluorine3.08(10)297(10)Janousek & Brauman (1979)
Cl2Dichlorine2.35(8)227(8)Janousek & Brauman (1979)
Br2Dibromine2.53(8)244(8)Janousek & Brauman (1979)
I2Diiodine2.524(5)243.5(5)Zanni et al. (1997)
IBrIodine monobromide2.512(3)242.4(4)Sheps, Miller & Lineberger (2009)
LiClLithium chloride0.593(10)57.2(10)Miller et al. (1986)
FeOIron(II) oxide1.4950(5)144.25(6)Kim, Weichman & Neumark (2015)
CNCyano radical3.862(4)372.6263[72][73][74]
Triatomics
NO2Nitrogen dioxide2.273(5)219.3(5)Ervin, Ho & Lineberger (1988)
O3Ozone2.1028(25)202.89(25)Novick et al. (1979)
SO2Sulfur dioxide1.107(8)106.8(8)Nimlos & Ellison (1986)
Larger polyatomics
CH2CHOVinyloxy1.8248(+2-6)176.07(+3-7)Rienstra-Kiracofe et al. (2002) after Mead et al. (1984)
C6H6Benzene−0.70(14)−68(14)Ruoff et al. (1995)
C6H4O2p-Benzoquinone1.860(5)179.5(6)Schiedt & Weinkauf (1999)
BF3Boron trifluoride2.65(10)256(10)Page & Goode (1969)
HNO3Nitric acid0.57(15)55(14)Janousek & Brauman (1979)
CH3NO2Nitromethane0.172(6)16.6(6)Adams et al. (2009)
POCl3Phosphoryl chloride1.41(20)136(20)Mathur et al. (1976)
SF6Sulfur hexafluoride1.03(5)99.4(49)Troe, Miller & Viggiano (2012)
C2(CN)4Tetracyanoethylene3.17(20)306(20)Chowdhury & Kebarle (1986)
WF6Tungsten hexafluoride3.5(1)338(10)George & Beauchamp (1979)
UF6Uranium hexafluoride5.06(20)488(20)NIST chemistry webbook after Borshchevskii et al. (1988)
C60Buckminsterfullerene2.6835(6)258.92(6)Huang et al. (2014)
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Second and third electron affinity

More information Z, Element ...
ZElementNameElectron affinity (eV)Electron affinity (kJ/mol)References
7NNitrogen−6.98−673[75]
7N2−Nitrogen−11.09−1070[75]
8OOxygen−7.71−744[75]
15PPhosphorus−4.85−468[75]
15P2−Phosphorus−9.18−886[75]
16SSulfur−4.73−456[75]
33AsArsenic−4.51−435[75]
33As2−Arsenic−8.31−802[75]
34SeSelenium−4.25−410[75]
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Bibliography

  • Janousek, Bruce K.; Brauman, John I. (1979), "Electron affinities", in Bowers, M. T. (ed.), Gas Phase Ion Chemistry, vol. 2, New York: Academic Press, p. 53.
  • Rienstra-Kiracofe, J.C.; Tschumper, G.S.; Schaefer, H.F.; Nandi, S.; Ellison, G.B. (2002), "Atomic and molecular electron affinities: Photoelectron experiments and theoretical computations", Chem. Rev., vol. 102, no. 1, pp. 231–282, doi:10.1021/cr990044u, PMID 11782134.
  • Updated values can be found in the NIST chemistry webbook for around three dozen elements and close to 400 compounds.

Specific molecules

References

See also

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