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Potassium dithioferrate

Chemical compound From Wikipedia, the free encyclopedia

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Potassium dithioferrate is the inorganic compound with the formula KFeS2. It is a purple solid that is insoluble in water. Regarding its chemical structure, the compound consists of infinite chains of edge-shared anionic FeS4 tetrahedra. Associated with these chains are potassium ions.[1] A related family of one-dimensional materials exists with the formula MFe2S3 (M = K, Rb, Cs). These mixed-valence compounds are represented by the mineral rasvumite, KFe2S3.[2]

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The compound is prepared by heating iron powder, sulfur, and potassium carbonate at 900 °C. According to the idealized stoichiometry, this reaction is proposed to cogenerate potassium sulfate:[3]

6 Fe + 13 S + 4 K2CO3 → 6 KFeS2 + K2SO4 + 4 CO2
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