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Tetramethylammonium auride

Chemical compound From Wikipedia, the free encyclopedia

Tetramethylammonium auride
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Tetramethylammonium auride, (CH3)4NAu, is an ionic compound containing tetramethylammonium as cation and gold in a –1 oxidation state as anion. It is an example of a compound containing this rare ionic form of gold, and the first auride paired with a cation that is not a metal atom that has been synthesized.[1]

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Production

Tetramethylammonium auride can be made from caesium auride dissolved in liquid ammonia reacting with tetramethylammonium chloride or an ion exchange resin.[1]

Properties

Tetramethylammonium auride decomposes over the period of a day at room temperature to form gold. However it is stable at −55°C. Crystals are transparent.[1]

The crystal structure is tetragonal with space group P4/nmm. Unit dell dimensions are a = 7.599, c = 5.433 Å with volume V = 313.7 Å3, Z = 2 formulas per unit cell.[1]

References

Further reading

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