മെഥനോൾ
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CH3OH എന്ന തന്മാത്രാ ഘടനയുള്ള രാസവസ്തുവാണ് മെഥനോൾ, ( മീഥൈൽ ആൽക്കഹോൾ / വുഡ് ആൽക്കഹോൾ / വുഡ് നാഫ്ത / വൂഡ് സ്പിരിറ്റ്) [17]
വസ്തുതകൾ Names, Identifiers ...
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Names | |||
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Preferred IUPAC name
Methanol[1] | |||
Other names
Carbinol Columbian spirits Hydroxymethane MeOH Methyl alcohol Methyl hydrate Methyl hydroxide Methylic alcohol Methylol Methylene hydrate, primary alcohol Pyroligneous spirit Wood alcohol Wood naphtha Wood spirit | |||
Identifiers | |||
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3D model (JSmol) |
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Beilstein Reference | 1098229 | ||
ChEBI | |||
ChEMBL | |||
ChemSpider |
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ECHA InfoCard | 100.000.599 | ||
EC Number |
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Gmelin Reference | 449 | ||
KEGG |
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MeSH | {{{value}}} | ||
PubChem CID |
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RTECS number |
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UNII | |||
UN number | 1230 | ||
CompTox Dashboard (EPA) |
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InChI | |||
SMILES | |||
Properties | |||
CH3OH | |||
Molar mass | 32.042 g·mol−1 | ||
Appearance | Colourless liquid | ||
Odor | Faint and similar to ethanol | ||
സാന്ദ്രത | 0.792 g/cm3[2] | ||
ദ്രവണാങ്കം | |||
ക്വഥനാങ്കം | 64.7 °C (148.5 °F; 337.8 K) | ||
miscible | |||
log P | −0.69 | ||
ബാഷ്പമർദ്ദം | 13.02 kPa (at 20 °C) | ||
Acidity (pKa) | 15.5[3] | ||
Conjugate acid | Methyloxonium[4] | ||
Conjugate base | Methanolate[5] | ||
−21.40·10−6 cm3/mol | |||
Refractive index (nD) |
1.33141[6] | ||
വിസ്കോസിറ്റി | 0.545 mPa·s (at 25 °C)[7] | ||
Dipole moment |
1.69 D | ||
Thermochemistry | |||
Heat of combustion, higher value (HHV) |
725.7 kJ/mol, 173.4 kcal/mol, 5.77 kcal/g | ||
Hazards[8][9] | |||
Occupational safety and health (OHS/OSH): | |||
Main hazards |
Methanol and its vapours are flammable.
Moderately toxic for small animals – Highly toxic to large animals and humans (in high concentrations) – May be fatal/lethal or cause blindness and damage to the liver, kidneys, and heart if swallowed – Toxicity effects from repeated over exposure have an accumulative effect on the central nervous system, especially the optic nerve – Symptoms may be delayed, become severe after 12 to 18 hours, and linger for several days after exposure[10] | ||
GHS labelling: | |||
Pictograms |
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Signal word |
Danger[11] | ||
Hazard statements |
H225, H301, H302, H305, H311, H331, H370[11] | ||
Precautionary statements |
P210, P233, P235, P240, P241, P242, P243, P260, P264, P270, P271, P280, P301+P330+P331, P302+P352, P303+P361+P353, P304+P340, P305+P351+P338, P307+P311, P310, P311, P312, P337+P313, P361, P363, P370+P378, P403+P233, P405, P501[11] | ||
NFPA 704 (fire diamond) | |||
Flash point | 11- തൊട്ട് 12 °C (52- തൊട്ട് 54 °F; 284- തൊട്ട് 285 K) | ||
Autoignition temperature |
470 °C (878 °F; 743 K)[13] 385 °C (725 °F; 658 K)[14] | ||
Explosive limits | 6–36%[15] | ||
Lethal dose or concentration (LD, LC): | |||
LD50 (median dose) |
5628 mg/kg (rat, oral) 7300 mg/kg (mouse, oral) 12880 mg/kg (rat, oral) 14200 mg/kg (rabbit, oral)[16] | ||
LC50 (median concentration) |
64,000 ppm (rat, 4 h)[16] | ||
LCLo (lowest published) |
33,082 ppm (cat, 6 h) 37,594 ppm (mouse, 2 h)[16] | ||
NIOSH (US health exposure limits): | |||
PEL (Permissible) |
TWA 200 ppm (260 mg/m3)[15] | ||
REL (Recommended) |
TWA 200 ppm (260 mg/m3) ST 250 ppm (325 mg/m3) [skin][15] | ||
IDLH (Immediate danger) |
6000 ppm[15] | ||
Safety data sheet (SDS) | |||
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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